I would say that you can leave in on all the time, regardless of break-in period.
In the end, your automatic transmission is still: automatic. That is, it will do what it deems most appropriate for the car according to the current conditions.
With ECT PWR "on", it will "kickdown" more readily. However, in terms of holding upshifts longer, I don't think it's a "set" schedule that is "shifted up in rpm" by a set amount--I mean, it still takes into account the throttle position and makes its own judgements still.
If you were worried about not exceeding a certain RPM (say, 4000) during your break-in period, that would depend more on your foot's "will" than the ECT PWR shifting schedule.
The ECT PWR "on" WILL affect your overall gas mileage and reduce it somewhat, though.